Mourinho was drafted into Team Shearer’s team as a goalkeeper for the match – which was aiming to raise funds for those affected by the Grenfell Tower disaster.
He made an immediate impact after coming on from the bench and even scored a penalty during the shoot-out.
Following the clash, Mourinho appeared in the studio alongside Mo Farah – who also played.
He was seen tapping the leg of the long distance legend’s leg, before saying: “I did to you Thierry Henry and Jamie Carragher did.
“I’m sorry, I’m sorry.”
Cue rapturous laughter from everyone inside the studio.
And the moment also proved a massive hit with fans watching.
“Jose Mourinho just tried to do the Jamie Carragher/Thierry Henry knee touch with Mo Farah. What wonderful TV,” one commented.
Another wrote: “Mourinho is just too funny.”
While a third added: “Mourinho is simply a legend.”
The ex-Chelsea boss also caused comedy gold before the match, when Alan Shearer made a hilarious joke in the dressing room.